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DC Field | Value | Language |
---|---|---|
dc.contributor.author | Dalvi, Anshuman | - |
dc.date.accessioned | 2024-01-25T07:08:30Z | - |
dc.date.available | 2024-01-25T07:08:30Z | - |
dc.date.issued | 2005-05 | - |
dc.identifier.uri | https://www.sciencedirect.com/science/article/pii/S0022369704003841 | - |
dc.identifier.uri | http://dspace.bits-pilani.ac.in:8080/jspui/xmlui/handle/123456789/13983 | - |
dc.description.abstract | Crystallization in the melt-quenched (MQ) and mechanically milled (MM) superionic systems has been thoroughly investigated using differential scanning calorimetry, X-ray diffraction and electrical conductivity measurements. It is observed that the two systems obey different crystallization processes. The conventionally melt-quenched samples exhibit only one crystallization peak near 112 °C, whereas, the mechanochemically synthesized samples show two well-separated crystallization peaks at Tcl∼75–97 °C and Tc2∼132±2 °C. The higher value of electrical conductivity in the mechanochemically synthesized samples (∼10−2 Ω−1 cm−1 at 300 K) than the melt-quenched samples is attributed to the higher value of disorder (entropy) in the former. | en_US |
dc.language.iso | en | en_US |
dc.publisher | Elsevier | en_US |
dc.subject | Physics | en_US |
dc.subject | A. Amorphous materials | en_US |
dc.subject | C. Glasses | en_US |
dc.subject | C. Differential scanning calorimetry | en_US |
dc.subject | Phase transitions | en_US |
dc.title | Crystallization studies on AgI–Ag2O–MoO3 superionic system synthesized by melt quenching and mechanical milling | en_US |
dc.type | Article | en_US |
Appears in Collections: | Department of Physics |
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