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DC Field | Value | Language |
---|---|---|
dc.contributor.author | Grover, Nitika | - |
dc.date.accessioned | 2024-08-10T04:37:00Z | - |
dc.date.available | 2024-08-10T04:37:00Z | - |
dc.date.issued | 2019-02 | - |
dc.identifier.uri | https://pubs.acs.org/doi/full/10.1021/acs.inorgchem.8b03106 | - |
dc.identifier.uri | http://dspace.bits-pilani.ac.in:8080/jspui/xmlui/handle/123456789/15188 | - |
dc.description.abstract | A new series of mixed β-substituted dibenzoporphyrins were synthesized, and the effect of β-substitution on the spectral and electrochemical redox properties of the macrocycle was elucidated. The synthetic route to β-tetrasubstituted dibenzoporphyrins begins with the regioselective bromination of NiTPP(Benzo)2 to afford NiTPP(Benzo)2Br4, followed by Pd catalyzed coupling reaction to access NiTPP(Benzo)2(R)4 (R = phenyl (Ph) and phenylethynyl (PE)). Synthesized benzoporphyrins exhibited red-shifted absorption spectral features with tunable redox properties. These benzoporphyrins displayed pronounced electronic effects of β-substituents on the macrocyclic skeleton. NiTPP(Benzo)2(PE)4 exhibited the lowest HOMO–LUMO gap among the series due to extended π-conjugation. Intrestingly, metal-centered oxidation of Ni(II)/Ni(III) was observed for NiOPP(Benzo)2 and NiOPP(Benzo)Br2 after an initial conversion of the neutral porphyrin to its dicationic form under electrochemical conditions. | en_US |
dc.language.iso | en | en_US |
dc.publisher | ACS | en_US |
dc.subject | Chemistry | en_US |
dc.subject | Conformational Dynamics | en_US |
dc.subject | Oxidation | en_US |
dc.subject | Pyrroles | en_US |
dc.subject | Redox reactions | en_US |
dc.title | β-Functionalized Dibenzoporphyrins with Mixed Substituents Pattern: Facile Synthesis, Structural, Spectral, and Electrochemical Redox Properties | en_US |
dc.type | Article | en_US |
Appears in Collections: | Department of Chemistry |
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