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Please use this identifier to cite or link to this item: http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/15518
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dc.contributor.authorKumar, Anil-
dc.date.accessioned2024-09-11T03:57:13Z-
dc.date.available2024-09-11T03:57:13Z-
dc.date.issued2021-01-
dc.identifier.urihttps://pubs.acs.org/doi/10.1021/acs.joc.0c02467-
dc.identifier.urihttp://dspace.bits-pilani.ac.in:8080/jspui/xmlui/handle/123456789/15518-
dc.description.abstractA Rh(III)-catalyzed dehydrogenative annulation and spirocyclization of 2-arylindoles and 2-(1H-pyrazol-1-yl)-1H-indole with maleimides is described. The cascade protocol provided highly functionalized benzo[a]pyrrolo[3,4-c]carbazole-1,3(2H,8H)-diones and spiro[isoindolo[2,1-a]indole-6,3′-pyrrolidine]-2′,5′-diones in good to excellent. The developed reaction methodology exhibited broad substrate scope with good functional group tolerance and is operationally simple and scalable. Photophysical properties of the annulated products were investigated. The annulated product of 2-(1H-pyrazol-1-yl)-1H-indole showed high absorption and emission values with a large red-shift as compared to that of 2-phenylindoleen_US
dc.language.isoenen_US
dc.publisherACSen_US
dc.subjectChemistryen_US
dc.subjectAbsorptionen_US
dc.subjectAnnulationsen_US
dc.subjectCatalystsen_US
dc.subjectChemical reactionsen_US
dc.subjectIndolesen_US
dc.titleRhodium(III)-Catalyzed Dehydrogenative Annulation and Spirocyclization of 2-Arylindoles and 2-(1H-Pyrazol-1-yl)-1H-indoles with Maleimides: A Facile Access to Isogranulatimide Alkaloid Analoguesen_US
dc.typeArticleen_US
Appears in Collections:Department of Chemistry

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