Electrochemical Oxidative Coupling Between Benzylic C(sp3)–H and N–H of Secondary Amines: Rapid Synthesis of α-Amino α-Aryl Esters

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DC Field	Value	Language
dc.contributor.author	Kumar, Indresh	-
dc.date.accessioned	2024-09-12T09:34:36Z	-
dc.date.available	2024-09-12T09:34:36Z	-
dc.date.issued	2021-06	-
dc.identifier.uri	https://pubs.acs.org/doi/full/10.1021/acs.joc.1c00944	-
dc.identifier.uri	http://dspace.bits-pilani.ac.in:8080/jspui/xmlui/handle/123456789/15552	-
dc.description.abstract	An intermolecular electrochemical coupling between the benzylic C(sp3)–H bond and various secondary amines is reported. The electronic behavior of two electronically rich units viz the α-position of α-aryl acetates and amines was engineered electrochemically, thus facilitating their reactivity for the direct access of α-amino esters. A series of acyclic/cyclic secondary amines and α-aryl acetates were tested to furnish the corresponding α-amino esters with high yields (up to 92%) under mild conditions.	en_US
dc.language.iso	en	en_US
dc.publisher	ACS	en_US
dc.subject	Chemistry	en_US
dc.subject	Amines	en_US
dc.subject	Fossil fuels	en_US
dc.subject	Organic compounds	en_US
dc.subject	Purification	en_US
dc.title	Electrochemical Oxidative Coupling Between Benzylic C(sp3)–H and N–H of Secondary Amines: Rapid Synthesis of α-Amino α-Aryl Esters	en_US
dc.type	Article	en_US
Appears in Collections:	Department of Chemistry

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