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Please use this identifier to cite or link to this item: http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/15552
Title: Electrochemical Oxidative Coupling Between Benzylic C(sp3)–H and N–H of Secondary Amines: Rapid Synthesis of α-Amino α-Aryl Esters
Authors: Kumar, Indresh
Keywords: Chemistry
Amines
Fossil fuels
Organic compounds
Purification
Issue Date: Jun-2021
Publisher: ACS
Abstract: An intermolecular electrochemical coupling between the benzylic C(sp3)–H bond and various secondary amines is reported. The electronic behavior of two electronically rich units viz the α-position of α-aryl acetates and amines was engineered electrochemically, thus facilitating their reactivity for the direct access of α-amino esters. A series of acyclic/cyclic secondary amines and α-aryl acetates were tested to furnish the corresponding α-amino esters with high yields (up to 92%) under mild conditions.
URI: https://pubs.acs.org/doi/full/10.1021/acs.joc.1c00944
http://dspace.bits-pilani.ac.in:8080/jspui/xmlui/handle/123456789/15552
Appears in Collections:Department of Chemistry

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