Regiodivergent Synthesis of Cinnoline-Fused Indazolones through Pd-Catalyzed Annulation of 1-Arylindazolones with Allenoates

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DC Field	Value	Language
dc.contributor.author	Sakhuja, Rajeev	-
dc.date.accessioned	2024-09-13T09:03:20Z	-
dc.date.available	2024-09-13T09:03:20Z	-
dc.date.issued	2022-01	-
dc.identifier.uri	https://pubs.acs.org/doi/10.1021/acs.joc.1c02629	-
dc.identifier.uri	http://dspace.bits-pilani.ac.in:8080/jspui/xmlui/handle/123456789/15571	-
dc.description.abstract	A tender-hearted Pd(II)-catalyzed C–H activation of 1-arylindazolones followed by an oxidative [4 + 2] annulation reaction has been accomplished, engaging allenoates as annulating partners. Using this strategy, two different regioisomeric forms of cinnoline-fused indazolones possessing internal and exocyclic double bonds were synthesized in acetic acid and dioxane, respectively. Mild and aerobic conditions, avoiding the use of any metal–oxidant, highlights the rewards of this oxidative annulation protocol.	en_US
dc.language.iso	en	en_US
dc.publisher	ACS	en_US
dc.subject	Chemistry	en_US
dc.subject	Synthesis	en_US
dc.subject	Cinnoline-Fused	en_US
dc.title	Regiodivergent Synthesis of Cinnoline-Fused Indazolones through Pd-Catalyzed Annulation of 1-Arylindazolones with Allenoates	en_US
dc.type	Article	en_US
Appears in Collections:	Department of Chemistry

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