DSpace logo

Please use this identifier to cite or link to this item: http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/16939
Full metadata record
DC FieldValueLanguage
dc.contributor.authorAyscough, P. B.-
dc.contributor.authorOversby, J. P.-
dc.date.accessioned2025-01-30T10:53:29Z-
dc.date.available2025-01-30T10:53:29Z-
dc.date.issued1972-
dc.identifier.urihttp://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/16939-
dc.description.abstractSome of the reactions occurring during they-radiolysis of a number of carboxylic esters at cryogenic temperatures have been identified by studying the e.s.r. spectra of trapped intermediate radicals. It appears that the capture of thermal electrons by the ester molecule is followed by dissociation of the radical-anion by one of two possible processes, each leading to the formation of alkyl radicals. Secondary radicals formed by abstraction of hydrogen from the ester appear during thermal annealing. Ultraviolet irradiation of these radicals leads to the regeneration of alkyl radicals. Hydrogen atoms produced by ultra-violet irradiation of mixtures of hydrogen sulphide and carboxylic esters react to give alkyl and acyl radicals, by a mechanism similar to that proposed for carboxylic acids.en_US
dc.publisherJournal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (7)en_US
dc.subjectChemistryen_US
dc.subjectElectron Spin Resonanceen_US
dc.subjectJournal of the Chemical Society : Faraday Transaction - Ien_US
dc.titleElectron Spin Resonance Studies of Elementary Processes in Radiation- and Photo-chemistry: Part 9.—Carboxylic Esters at Cryogenic Temperaturesen_US
dc.typeArticleen_US
Appears in Collections:Journal Articles (before-1995)

Files in This Item:
File Description SizeFormat 
1153-1163.pdf
  Restricted Access
796.53 kBAdobe PDFView/Open Request a copy


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.