DSpace logo

Please use this identifier to cite or link to this item: http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/16954
Title: E.M.F. Measurements with Solid Electrolyte Galvanic Cells on the Calcium Oxide+Zirconia System: Determination of the Phase Relationships
Authors: Pizzini, S.
Morlotti, R.
Keywords: Electromotive Force Measurements
Solid Electrolyte Galvanic Cells
Calcium Oxide (CaO)
Zirconia (ZrO₂)
Journal of the Chemical Society : Faraday Transaction - I
Issue Date: 1972
Publisher: Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (9)
Abstract: E.m.f. measurements on the cell Pt | O2| CaO(+ CaF2)‖ CaF2(tF–= I)‖ ZrO2–CaO | O2| Pt have been carried out in the temperature range 900–1100°C to measure thermodynamic parameters of the lime + zirconia solid solutions and, possibly, to obtain complementary information on the phase-relationships across the concentration range investigated. Results show that the cubic field ranges only between xCaO= 0.14 and 0.17 and that at xCaO= 0.2 a CaZr4O9 phase is probably present. The results are discussed and compared with published data on the topic.
URI: http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/16954
Appears in Collections:Journal Articles (before-1995)

Files in This Item:
File Description SizeFormat 
1601-1610.pdf
  Restricted Access
1.01 MBAdobe PDFView/Open Request a copy


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.