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http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/16954
Title: | E.M.F. Measurements with Solid Electrolyte Galvanic Cells on the Calcium Oxide+Zirconia System: Determination of the Phase Relationships |
Authors: | Pizzini, S. Morlotti, R. |
Keywords: | Electromotive Force Measurements Solid Electrolyte Galvanic Cells Calcium Oxide (CaO) Zirconia (ZrO₂) Journal of the Chemical Society : Faraday Transaction - I |
Issue Date: | 1972 |
Publisher: | Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (9) |
Abstract: | E.m.f. measurements on the cell Pt | O2| CaO(+ CaF2)‖ CaF2(tF–= I)‖ ZrO2–CaO | O2| Pt have been carried out in the temperature range 900–1100°C to measure thermodynamic parameters of the lime + zirconia solid solutions and, possibly, to obtain complementary information on the phase-relationships across the concentration range investigated. Results show that the cubic field ranges only between xCaO= 0.14 and 0.17 and that at xCaO= 0.2 a CaZr4O9 phase is probably present. The results are discussed and compared with published data on the topic. |
URI: | http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/16954 |
Appears in Collections: | Journal Articles (before-1995) |
Files in This Item:
File | Description | Size | Format | |
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1601-1610.pdf Restricted Access | 1.01 MB | Adobe PDF | View/Open Request a copy |
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