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http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/16967| Title: | γ-Radiolysis of Diethyl Succinate |
| Authors: | Mills, K. J. Nosworthy Peto, J. M. |
| Keywords: | Chemistry γ-Radiolysis Diethyl Succinate Radiation Chemistry Radical Reactions Journal of the Chemical Society : Faraday Transaction - I |
| Issue Date: | 1972 |
| Publisher: | Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (9) |
| Abstract: | Diethyl succinate has been irradiated under vacuum with 60Co γ-radiation. An attempt was made to identify and measure the complete product spectrum. Twenty different products were found after a maximum total dose of 9 × 1023 eV l.–1. The most abundant were ethanol, ethyl propionate, ethane, hydrogen, carbon monoxide, acetaldehyde and carbon dioxide. With the possible exception of acetaldehyde, G-values for these products were independent of the dose in the range studied. Gas yields were also measured in the presence of small amounts of additives (FeCl3, H2O or CH2 : CH2). Possible mechanisms for product formation are discussed. |
| URI: | http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/16967 |
| Appears in Collections: | Journal Articles (before-1995) |
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| File | Description | Size | Format | |
|---|---|---|---|---|
| 1626-1634.pdf Restricted Access | 611.98 kB | Adobe PDF | View/Open Request a copy |
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