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http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17001| Title: | Addition of Formaldehyde to Slowly Reacting Hydrogen + Oxygen Mixtures |
| Authors: | Baldwin, R R Fuller, A R Walker, R W |
| Keywords: | Chemistry Formaldehyde Hydrogen Oxygen Mixtures Journal of the Chemical Society : Faraday Transaction - I |
| Issue Date: | 1972 |
| Publisher: | Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (7) |
| Abstract: | The effect of HCHO in reducing the induction periods of H2+ O2+ N2 mixtures at 500°C has been examined for a range of mixture composition, using HCHO concentrations in the range 0.05–1.0 %. Computer treatment shows that the marked reduction can only be accounted for by the reaction HO2+ HCHO = H2O2+ HCO(24). A detailed computer analysis of the results for a range of mixtures gives the ratio k24/k½10= 23 (mol l.–1 s)–½. Taking k10(HO2+ HO2= H2O2+ O2)= 1.8 × 109 gives k24= 9.6 × 105 l.mol–1 s–1. With A24= 109, this corresponds to E24= 10.7 kcal mol–1. |
| URI: | http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17001 |
| Appears in Collections: | Journal Articles (before-1995) |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| 1362-1367.pdf Restricted Access | 500.7 kB | Adobe PDF | View/Open Request a copy |
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