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dc.contributor.authorBaldwin, R R-
dc.contributor.authorFuller, A R-
dc.contributor.authorWalker, R W-
dc.date.accessioned2025-01-31T11:32:28Z-
dc.date.available2025-01-31T11:32:28Z-
dc.date.issued1972-
dc.identifier.urihttp://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17001-
dc.description.abstractThe effect of HCHO in reducing the induction periods of H2+ O2+ N2 mixtures at 500°C has been examined for a range of mixture composition, using HCHO concentrations in the range 0.05–1.0 %. Computer treatment shows that the marked reduction can only be accounted for by the reaction HO2+ HCHO = H2O2+ HCO(24). A detailed computer analysis of the results for a range of mixtures gives the ratio k24/k½10= 23 (mol l.–1 s)–½. Taking k10(HO2+ HO2= H2O2+ O2)= 1.8 × 109 gives k24= 9.6 × 105 l.mol–1 s–1. With A24= 109, this corresponds to E24= 10.7 kcal mol–1.en_US
dc.language.isoenen_US
dc.publisherJournal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (7)en_US
dc.subjectChemistryen_US
dc.subjectFormaldehydeen_US
dc.subjectHydrogenen_US
dc.subjectOxygen Mixturesen_US
dc.subjectJournal of the Chemical Society : Faraday Transaction - Ien_US
dc.titleAddition of Formaldehyde to Slowly Reacting Hydrogen + Oxygen Mixturesen_US
dc.typeArticleen_US
Appears in Collections:Journal Articles (before-1995)

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