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Title: Effect of the Solution Vapour Pressure on the Temperature Dependence of the Dissociation Constant of Acetic Acid in Water
Authors: Lown, D. A.
Thirsk, H. R.
Keywords: Chemistry
Electrochemistry
Dissociation Constant
Journal of the Chemical Society : Faraday Transaction - I
Issue Date: 1972
Publisher: Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (10)
Abstract: The dissociation constant of acetic acid in water is between 4 and 26% greater at the solution vapour pressure than at one atmosphere in the range 250 to 374°C. K = /(T)s.v.P. corresponds to neither the isobaric nor isochoric conditions, and the error introduced by neglecting the effect of the vapour pressure on the equilibrium at high temperatures is discussed.
URI: http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17013
Appears in Collections:Journal Articles (before-1995)

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