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Title: | Effect of the Solution Vapour Pressure on the Temperature Dependence of the Dissociation Constant of Acetic Acid in Water |
Authors: | Lown, D. A. Thirsk, H. R. |
Keywords: | Chemistry Electrochemistry Dissociation Constant Journal of the Chemical Society : Faraday Transaction - I |
Issue Date: | 1972 |
Publisher: | Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (10) |
Abstract: | The dissociation constant of acetic acid in water is between 4 and 26% greater at the solution vapour pressure than at one atmosphere in the range 250 to 374°C. K = /(T)s.v.P. corresponds to neither the isobaric nor isochoric conditions, and the error introduced by neglecting the effect of the vapour pressure on the equilibrium at high temperatures is discussed. |
URI: | http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17013 |
Appears in Collections: | Journal Articles (before-1995) |
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