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http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17032| Title: | Comparison of the Transport Properties of Normal and Expanded Forms of a Cation-exchange Membrane: Part 3—Application of Irreversible Thermodynamics and Nernst-Planck Theories to Membranes in Concentrated NaCl Solutions |
| Authors: | Gardner, Colin R. Paterson, Russell |
| Keywords: | Chemistry Transport Properties Cation-Exchange Membranes Irreversible Thermodynamics Nernst-Planck Theory Journal of the Chemical Society : Faraday Transaction - I |
| Issue Date: | 1972 |
| Publisher: | Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (11) |
| Abstract: | The Onsager mobility and frictional coefficients for the normal and expanded membranes have been calculated when the external solution was 1.0 M NaCl. The validity of a number of methods of approximation of minor coefficients is examined. The results have been reproduced using a ternary electrolyte calculation in which mobility coefficients for the salt-free membrane were combined with those of aqueous sodium chloride. Calculated transport measurements agree well with those obtained experimentally. Finally the validity and probable errors of the Nernst-Planck theory are examined. |
| URI: | http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17032 |
| Appears in Collections: | Journal Articles (before-1995) |
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| 2030-2040.pdf Restricted Access | 893.46 kB | Adobe PDF | View/Open Request a copy |
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