Flash Photolysis of HiS

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DC Field	Value	Language
dc.contributor.author	Langford, R B	-
dc.contributor.author	Oldershaw, G A	-
dc.date.accessioned	2025-02-03T11:55:13Z	-
dc.date.available	2025-02-03T11:55:13Z	-
dc.date.issued	1972	-
dc.identifier.uri	http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17105	-
dc.description.abstract	Hydrogen atoms produced by flash photolysis of H2S are “hot” and react with CO2 by process (13). H + CO2→CO + OH, ΔH= 102 kJ mol–1(13) Flash spectroscopy has been used to determine [SH] and [S2] as functions of time following flash photolysis of H2S diluted with CO2. The rate-determining step in the decay of SH is either (3) or (4), with k3= 1 × 10–11 or k4= 3 × 10–11 cm3 molecule–1 s–1. The removal of S2 occurs principally by reaction (8), which is third order over the range of pressures studied, and the order of magnitude of k8 is 2.5 × 10–30 cm6 molecule–2 s–1. H + SH→H2+ S (3), 2SH→H2S + S (4), 2S2+ CO2→S4+ CO2. (8)	en_US
dc.language.iso	en	en_US
dc.publisher	Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (8)	en_US
dc.subject	Chemistry	en_US
dc.subject	Flash Photolysis	en_US
dc.subject	H2S	en_US
dc.subject	Journal of the Chemical Society : Faraday Transaction - I	en_US
dc.title	Flash Photolysis of HiS	en_US
dc.type	Article	en_US
Appears in Collections:	Journal Articles (before-1995)

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