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http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17109| Title: | Thermal Decomposition of Ethyl, Isopropyl and t-Butyl Fluorides in the Gas Phase |
| Authors: | Dastoor, P. N. Emovon, E. U. |
| Keywords: | Chemistry Thermal Decomposition Alkyl Fluorides Gas-Phase Reactions Reaction Kinetics Journal of the Chemical Society : Faraday Transaction - I |
| Issue Date: | 1972 |
| Publisher: | Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (11) |
| Abstract: | Ethyl, isopropyl and t-butyl fluorides decompose in a flow system into hydrogen fluoride and the corresponding olefin by a predominantly molecular mechanism. The first order rate constants are given by the Arrhenius equations: ethyl fluoride (520–600°C) : k/s–1= 1012.16±0.04exp–59 200±2000/RT, isopropyl fluoride(445–522°C) : k/s–1= 1011.83±0.02 exp–53 900±800/RT, t-butyl fluoride (329–370°C) : k/s–1= 1013.96±0.01 exp–50 400±900/RT. |
| URI: | http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17109 |
| Appears in Collections: | Journal Articles (before-1995) |
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| File | Description | Size | Format | |
|---|---|---|---|---|
| 2098-2102.pdf Restricted Access | 393.09 kB | Adobe PDF | View/Open Request a copy |
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