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dc.contributor.authorParkes, David A.-
dc.date.accessioned2025-02-03T11:56:08Z-
dc.date.available2025-02-03T11:56:08Z-
dc.date.issued1972-
dc.identifier.urihttp://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17110-
dc.description.abstractThe negative ions formed in N2O and N2O and N2O + O2 mixtures have been studied in the gas phase using a drift tube and mass filter. Gas pressures were in the Torr range, and reduced fields were varied between 10–17 and 10–15 V cm2 molecule–1. The observed ion spectrum was found to be governed by the following reaction, with their associated thermal rate constants: e + N2O → N2+ O–, k1= 4 × 10–15 cm3 molecule–1 s–1, O–+ N2O → NO–+ NO, k3=(1.95 ± 0.06)× 10–10 cm3 molecule–1 s–1, NO–+ N2O → NO–2+ N2, k4=(2.8 ± 0.2)× 10–14 cm3 molecule–1 s–1, NO–+ 2N2O → N3O–2+ N2O, k5=(8.5 ± 1.5)× 10–30 cm6 molecule–2 s–1, O–+ 2N2O → N2O–2+ N2O, k6=(4.2 ± 0.5)× 10–29 cm6 molecule–2 s–1, NO–+ N2O → N2O + NO + e, k11=(6.0 ± 1.0)× 10–12 cm3 molecule–1 s–1, O–2+ N2O → O–3+ N2, k10 < 10–12 cm3 molecule–1 s–1. The rates of reaction, (5), (6) and (11) were weak functions of reduced field. In no experiment was any evidence found for the existence of a long-lived N2O– ion.en_US
dc.language.isoenen_US
dc.publisherJournal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (11)en_US
dc.subjectChemistryen_US
dc.subjectElectron Attachmenten_US
dc.subjectNegative Ion-Molecule Reactionsen_US
dc.subjectNitrous Oxideen_US
dc.subjectPlasma Chemistryen_US
dc.subjectJournal of the Chemical Society : Faraday Transaction - Ien_US
dc.titleElectron Attachment and Negative Ion-Molecule Reactions in Nitrous Oxideen_US
dc.typeArticleen_US
Appears in Collections:Journal Articles (before-1995)

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