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DC Field | Value | Language |
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dc.contributor.author | Parkes, David A. | - |
dc.date.accessioned | 2025-02-03T11:56:08Z | - |
dc.date.available | 2025-02-03T11:56:08Z | - |
dc.date.issued | 1972 | - |
dc.identifier.uri | http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17110 | - |
dc.description.abstract | The negative ions formed in N2O and N2O and N2O + O2 mixtures have been studied in the gas phase using a drift tube and mass filter. Gas pressures were in the Torr range, and reduced fields were varied between 10–17 and 10–15 V cm2 molecule–1. The observed ion spectrum was found to be governed by the following reaction, with their associated thermal rate constants: e + N2O → N2+ O–, k1= 4 × 10–15 cm3 molecule–1 s–1, O–+ N2O → NO–+ NO, k3=(1.95 ± 0.06)× 10–10 cm3 molecule–1 s–1, NO–+ N2O → NO–2+ N2, k4=(2.8 ± 0.2)× 10–14 cm3 molecule–1 s–1, NO–+ 2N2O → N3O–2+ N2O, k5=(8.5 ± 1.5)× 10–30 cm6 molecule–2 s–1, O–+ 2N2O → N2O–2+ N2O, k6=(4.2 ± 0.5)× 10–29 cm6 molecule–2 s–1, NO–+ N2O → N2O + NO + e, k11=(6.0 ± 1.0)× 10–12 cm3 molecule–1 s–1, O–2+ N2O → O–3+ N2, k10 < 10–12 cm3 molecule–1 s–1. The rates of reaction, (5), (6) and (11) were weak functions of reduced field. In no experiment was any evidence found for the existence of a long-lived N2O– ion. | en_US |
dc.language.iso | en | en_US |
dc.publisher | Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (11) | en_US |
dc.subject | Chemistry | en_US |
dc.subject | Electron Attachment | en_US |
dc.subject | Negative Ion-Molecule Reactions | en_US |
dc.subject | Nitrous Oxide | en_US |
dc.subject | Plasma Chemistry | en_US |
dc.subject | Journal of the Chemical Society : Faraday Transaction - I | en_US |
dc.title | Electron Attachment and Negative Ion-Molecule Reactions in Nitrous Oxide | en_US |
dc.type | Article | en_US |
Appears in Collections: | Journal Articles (before-1995) |
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2103-2120.pdf Restricted Access | 1.97 MB | Adobe PDF | View/Open Request a copy |
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