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Title: | Negative Ion Reactions in Nitrous Oxide-I-Carbon Dioxide Mixtures |
Authors: | Parkes, David A. |
Keywords: | Chemistry Negative Ion Reactions Nitrous Oxide Carbon Dioxide Mixtures Ion-Molecule Interactions Journal of the Chemical Society : Faraday Transaction - I |
Issue Date: | 1972 |
Publisher: | Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (11) |
Abstract: | The rate constants have been measured for the following reactions in N2O + CO2 mixtures at pressures in the Torr region, using a drift tube and mass filter: NO–+ 2CO2→ CO2·NO–+ CO2, k9= 7.5 × 10–29 cm6 molecule–2 s–1, NO–+ CO2→ NO + CO2+ e, k10= 1.0 × 10–11 cm3 molecule–1 s–1, NO–+ CO2+ N2O → CO–3+ N2+ NO, k12= 1.0 × 10–27 cm6 molecule–2 s–1, → N3O–2+ CO2, or → CO2·NO–+ NO2O, k13= 1.5 × 10–28 cm6 molecule–2 s–1. The results obtained here confirm the importance of collisional detachment from NO– in N2O negative ion chemistry. |
URI: | http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17111 |
Appears in Collections: | Journal Articles (before-1995) |
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