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http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17117| Title: | Infra-red Study of the Surface Properties of Rutile: Adsorption of Ethanol, n-Butanol and n-Hexanol |
| Authors: | Jackson, P Parfitt, G D |
| Keywords: | Chemistry Infra-red Study Surface Properties Rutile Journal of the Chemical Society : Faraday Transaction - I |
| Issue Date: | 1972 |
| Publisher: | Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (8) |
| Abstract: | The vapours of ethanol, n-butanol and n-hexanol chemisorb at room temperature on a variety of rutile surfaces. The adsorption is independent of the nature of the surface, and an estimate of the ethoxide population is 3 groups/nm2. Thermal decomposition of all three alkoxides was complete at 300°C producing surface carbonate species, with water and the respective alk-1-ene in the gas phase. A mechanism is proposed for the formation of the alk-1-ene. |
| URI: | http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17117 |
| Appears in Collections: | Journal Articles (before-1995) |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| 1443-1450.pdf Restricted Access | 1.15 MB | Adobe PDF | View/Open Request a copy |
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