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Please use this identifier to cite or link to this item: http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17163
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dc.contributor.authorChadwick, A. V.-
dc.contributor.authorSherwood, J. N.-
dc.date.accessioned2025-02-04T14:34:36Z-
dc.date.available2025-02-04T14:34:36Z-
dc.date.issued1972-
dc.identifier.urihttp://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17163-
dc.description.abstractA study has been made of the diffusion of the species 12C514C11H12 and 12C62H113H1 in single crystals of cyclohexane at 242 K. The measured diffusion coefficients are in good agreement with previously published values. An estimate of the isotope mass effect yields a value of the mass factor Eab= 0.003 ± 0.004. This virtually-zero value indicates that self-diffusion in cyclohexane proceeds by a complicated mechanism in which many molecules are involved ( >12). This discovery confirms previous speculations on the defect structure of the low entropy of fusion plastic solids.en_US
dc.language.isoenen_US
dc.publisherJournal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (1)en_US
dc.subjectChemistryen_US
dc.subjectLattice Defectsen_US
dc.subjectPlastic Organic Crystalsen_US
dc.subjectIsotope Mass Effectsen_US
dc.subjectSelf-Diffusion in Cyclohexaneen_US
dc.subjectJournal of the Chemical Society : Faraday Transaction - Ien_US
dc.titleLattice Defects in Plastic Organic Crystals: Part 7.—Isotope Mass Effects in Self-diffusion in Cyclohexaneen_US
dc.typeArticleen_US
Appears in Collections:Journal Articles (before-1995)

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