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Title: | Unstable Intermediates Part 107.—Radiation Damage Products in Choline Chloride 1 |
Authors: | Symons, M C R |
Keywords: | Chemistry Radiation Damage Choline Chloride Journal of the Chemical Society : Faraday Transaction - I |
Issue Date: | 1972 |
Publisher: | Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (2) |
Abstract: | At 77 K the major radicals detected by e.s.r. in y-irradiated cholinechloride [Mc3N4CH2CH2OHCI ] are CH2CH2OH, as previously suggested, and a species containing one hydrogen and one chlorine atom, closely resembling C1OH“. The latter was lost on annealing. Irradiation at room temperature gave only the radical Me3N+, which was rotating at this temperature, but stationary at 77 K. A mechanism is outlined which could account for these radicals and for the chain mechanism of the decomposition. |
URI: | http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17170 |
Appears in Collections: | Journal Articles (before-1995) |
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