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Please use this identifier to cite or link to this item: http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17204
Title: Mass Spectrometric Determination of the Thermodynamic Properties of the Vapour Species from Alumina
Authors: Farber, Milton
Srivastava, R. D.
Uy, O. M.
Keywords: Chemistry
Mass Spectrometric
Thermodynamic
Vapour Species
Alumina
Journal of the Chemical Society : Faraday Transaction - I
Issue Date: 1972
Publisher: Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (2)
Abstract: The vapour species over Al2O3(c) were determined mass spectrometrically from an alumina effusion cell. These data are in good agreement with previously published weight loss data since the partial pressures of the suboxides, AlO, Al2O, AlO2 and Al2O2 were found to be of the same order as those of the elements, Al and O. New values were determined for the ΔHf298K of AlO, Al2O, AlO2 and Al2O2 of 17.0 ± 2.0, –33.2 ± 3.0, –44.3 ± 2.0 and –113.6 ± 2.0 kcal/mol, respectively. Excellent agreement was obtained between second and third law studies.
URI: http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17204
Appears in Collections:Journal Articles (before-1995)

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