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Title: | Photochemistry of 1,3-DichIoro-tetrafluoroacetone: Part 2.—The Triplet State |
Authors: | Hackett, Peter A. Phillips, David |
Keywords: | Chemistry Photochemistry 1,3-DichIoro-tetrafluoroacetone Triplet State Journal of the Chemical Society : Faraday Transaction - I |
Issue Date: | 1972 |
Publisher: | Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (2) |
Abstract: | Quantum yields of S1→ T1 intersystem crossing in 1,3-dichloro-tetrafluoroacetone have been measured using the technique of biacetyl sensitization. The vibrationally-relaxed singlet state of the molecule intersystem crosses to a dissociative triplet with quantum yield 0.92. Vibrationally-excited singlet-state molecules do not intersystem cross, but may dissociate in two ways. |
URI: | http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17232 |
Appears in Collections: | Journal Articles (before-1995) |
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