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Title: Photochemistry of 1,3-DichIoro-tetrafluoroacetone: Part 2.—The Triplet State
Authors: Hackett, Peter A.
Phillips, David
Keywords: Chemistry
Photochemistry
1,3-DichIoro-tetrafluoroacetone
Triplet State
Journal of the Chemical Society : Faraday Transaction - I
Issue Date: 1972
Publisher: Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (2)
Abstract: Quantum yields of S1→ T1 intersystem crossing in 1,3-dichloro-tetrafluoroacetone have been measured using the technique of biacetyl sensitization. The vibrationally-relaxed singlet state of the molecule intersystem crosses to a dissociative triplet with quantum yield 0.92. Vibrationally-excited singlet-state molecules do not intersystem cross, but may dissociate in two ways.
URI: http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17232
Appears in Collections:Journal Articles (before-1995)

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