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DC Field | Value | Language |
---|---|---|
dc.contributor.author | Borrell, Peter | - |
dc.contributor.author | Cervenka, A | - |
dc.date.accessioned | 2025-02-05T15:04:50Z | - |
dc.date.available | 2025-02-05T15:04:50Z | - |
dc.date.issued | 1972 | - |
dc.identifier.uri | http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17234 | - |
dc.description.abstract | Additional results on the effect of additives on the product yields in the vapour-phase photolysis of trans-but-2-ene and cis-pent-2-ene are reported. They confirm, extend and reconcile our previous results with those of Chesick. The main photoreaction could be quenched by all additives at both wavelengths; at 203 nm, and with some additives at 185 nm, quenching was accompanied by photoisomerization. The effects can be correlated with the two states, Rydberg and V(π→π*), which are excited at the two wavelengths. Collisional deactivation of the V state results in photoisomerization while when the R state is deactivated no isomerization occurs. Apparently there is no ready collisional interconversion of the R and V states. | en_US |
dc.language.iso | en | en_US |
dc.publisher | Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (2) | en_US |
dc.subject | Chemistry | en_US |
dc.subject | Quenching | en_US |
dc.subject | Isomerization | en_US |
dc.subject | Photolysis | en_US |
dc.subject | Trans-But-2-ene | en_US |
dc.subject | Journal of the Chemical Society : Faraday Transaction - I | en_US |
dc.title | Quenching and Isomerization in the Photolysis of trans-But-2-ene and cis-Pent-2-ene at 185 nm and 203 nm | en_US |
dc.type | Article | en_US |
Appears in Collections: | Journal Articles (before-1995) |
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345-354.pdf Restricted Access | 1.14 MB | Adobe PDF | View/Open Request a copy |
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