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dc.contributor.authorBorrell, Peter-
dc.contributor.authorCervenka, A-
dc.date.accessioned2025-02-05T15:04:50Z-
dc.date.available2025-02-05T15:04:50Z-
dc.date.issued1972-
dc.identifier.urihttp://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17234-
dc.description.abstractAdditional results on the effect of additives on the product yields in the vapour-phase photolysis of trans-but-2-ene and cis-pent-2-ene are reported. They confirm, extend and reconcile our previous results with those of Chesick. The main photoreaction could be quenched by all additives at both wavelengths; at 203 nm, and with some additives at 185 nm, quenching was accompanied by photoisomerization. The effects can be correlated with the two states, Rydberg and V(π→π*), which are excited at the two wavelengths. Collisional deactivation of the V state results in photoisomerization while when the R state is deactivated no isomerization occurs. Apparently there is no ready collisional interconversion of the R and V states.en_US
dc.language.isoenen_US
dc.publisherJournal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (2)en_US
dc.subjectChemistryen_US
dc.subjectQuenchingen_US
dc.subjectIsomerizationen_US
dc.subjectPhotolysisen_US
dc.subjectTrans-But-2-eneen_US
dc.subjectJournal of the Chemical Society : Faraday Transaction - Ien_US
dc.titleQuenching and Isomerization in the Photolysis of trans-But-2-ene and cis-Pent-2-ene at 185 nm and 203 nmen_US
dc.typeArticleen_US
Appears in Collections:Journal Articles (before-1995)

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