Please use this identifier to cite or link to this item:
http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17300| Title: | Free Radical Addition to Olefins: Part 8.—Addition of of n-Heptafluoropropyl Radicals to Fluoro-ethylenes |
| Authors: | Tedder, J. M. Walton, J. C. Winton, K. D. R. |
| Keywords: | Chemistry Free Radical Addition n-Heptafluoropropyl Radicals Fluoroethylenes Radical Reactions Journal of the Chemical Society : Faraday Transaction - I |
| Issue Date: | 1972 |
| Publisher: | Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (1) |
| Abstract: | The light-induced addition of perfluoropropyl iodide to fluoro-ethylenes in the gas phase C3F7·+ RCH[double bond, length as m-dash]CH2→ C3F7CH2ĊHR (2) has been studied, and activation parameters determined by a competitive method. The corresponding differences found are: [graphic omitted] The most striking feature is the similarity to the results for addition of bromotrichloromethane to the same olefins. Relationships between activation energies and some theoretical quantities are discussed. |
| URI: | http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17300 |
| Appears in Collections: | Journal Articles (before-1995) |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| 160-166.pdf Restricted Access | 449.65 kB | Adobe PDF | View/Open Request a copy |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.