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Title: | Kinetics of ternary complex formation between nickel(II) species and pyridine-2-azo-p-dimethylaniline |
Authors: | Cobb, M. A. Hague, D. N. |
Keywords: | Chemistry Kinetics Ternary Complex Formation Nickel(II) Species Pyridine-2-azo-p-dimethylaniline Journal of the Chemical Society : Faraday Transaction - I |
Issue Date: | 1972 |
Publisher: | Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (5) |
Abstract: | The stopped-flow and temperature-jump relaxation methods have been used to measure the rate constants and activation parameters for the formation and the dissociation of the 1 : 1 complex between nickel(II) and pyridine-2-azo-p-dimethylaniline (PADA) and of the ternary complexes between PADA and the nickel(II)-polytriphosphate, -iminodiacetate, -N-methyliminodiacetate, -nitrilotriacetate, -diethylenetriamine, -triethylenetetramine and -2,2′,2″-triaminotriethylamine complexes. The rate constants at 25°C for the reaction between the Ni(II) complex of 1,4,8,11-tetra-azaundecane(2,3,2-tet) and NH3 are also reported. The series provides further evidence that the number of binding nitrogen atoms on the first ligand has a larger influence on ternary complex formation than its charge. |
URI: | http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17387 |
Appears in Collections: | Journal Articles (before-1995) |
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932-939.pdf Restricted Access | 1.49 MB | Adobe PDF | View/Open Request a copy |
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