Please use this identifier to cite or link to this item:
http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17410| Title: | Cryoscopic Comparison of Nitric and Deuteronitric Acids as Solvents |
| Authors: | Kureishi, A. W. Wyatt, P A H |
| Keywords: | Chemistry Cryoscopic Comparison Nitric Acid Deuteronitric Acids Journal of the Chemical Society : Faraday Transaction - I |
| Issue Date: | 1972 |
| Publisher: | Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (4) |
| Abstract: | DNO3 is found to have a freezing-point of –42.07°C, only 0.46 K lower than that of HNO3, and a molar enthalpy of fusion of 9917 ± 40 kJ mol–1(2370 ± 10 kcal mol–1), which is 5 % smaller than that of HNO3. The curvature of the freezing-point against molality of D2O (H2O) curve shows, however, that the extents of self-dissociation of the two acids are very similar, the total molality of dissociation products being about 0.85 in each case. As expected, KNO3 exhibits similar cryoscopic behaviour in the two solvents. Some results for other solutes in HNO3 are also reported: H2SO4 probably yields NO+2+ HSO–4+ H2O, while CH3COOH behaves as a non-electrolyte. |
| URI: | http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17410 |
| Appears in Collections: | Journal Articles (before-1995) |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| 676-682.pdf Restricted Access | 826.71 kB | Adobe PDF | View/Open Request a copy |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.