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Title: | Formation of Nitrous Acid in a Gas-phase Stirred Flow Reactor |
Authors: | Graham, R. F. Tyler, B. J. |
Keywords: | Chemistry Nitrous Acid Gas-phase Flow Reactor Journal of the Chemical Society : Faraday Transaction - I |
Issue Date: | 1972 |
Publisher: | Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (4) |
Abstract: | The gas-phase reaction between nitric oxide, nitrogen dioxide and water vapour to form nitrous acid has been studied in a stirred flow Pyrex reactor in the temperature range 298.2-328.2 K. Mixing in the reactor was promoted solely by the turbulent inlet jet and a close approximation to ideality was obtained. The reaction was followed by photometric measurement of the concentration of nitrogen dioxide in the reactor. Comparison of the results obtained at 298.2 K with those of previous workers confirms the suggested second-order dependence on water vapour pressure and shows the reaction to be heterogeneous. |
URI: | http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17411 |
Appears in Collections: | Journal Articles (before-1995) |
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