Please use this identifier to cite or link to this item:
http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17412| Title: | Reactions of Perfluoroethyl Radicals with Propane and Neopentane |
| Authors: | Whytock, D A |
| Keywords: | Chemistry Perfluoroethyl Radicals Propane Neopentane Journal of the Chemical Society : Faraday Transaction - I |
| Issue Date: | 1972 |
| Publisher: | Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (4) |
| Abstract: | The reactions of C2F5 radicals with neopentane and propane have been studied, using perfluoroethyl iodide as the free radical source. The Arrhenius parameters, based on A= 1013.36 cm3 mol–1 s–1 and E= 0 for the combination of C2F5 radicals, are: [graphic omitted] Analysis of the propyl iodides in the products allows calculation of the Arrhenius parameters for C2F5 attack at specific sites in the propane molecule, providing the values: [graphic omitted] Arrhenius parameters for hydrogen abstraction from alkanes by C2F5, CF3 and C2H5 radicals are compared; C2H5 is the least reactive whilst CF3 and C2F5 have similar reactivities. |
| URI: | http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17412 |
| Appears in Collections: | Journal Articles (before-1995) |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| 689-695.pdf Restricted Access | 1.27 MB | Adobe PDF | View/Open Request a copy |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.