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http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17451| Title: | Excited Products in the Photodissociation of Methyl Thiocyanate and Isothiocyanate in the Vacuum Ultra-violet |
| Authors: | D’Amario, P. Stefano, G. Di Lenzi, M. Mele, A. |
| Keywords: | Chemistry Photodissociation Methyl Thiocyanate and Isothiocyanate Vacuum Ultraviolet (VUV) Radiation Excited Products Journal of the Chemical Society : Faraday Transaction - I |
| Issue Date: | 1972 |
| Publisher: | Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (5) |
| Abstract: | Photolysis of CH3NCS and CH3SCN in the vacuum u.-v. produces fluorescence attributed to SCN excited radicals. In the case of CH3SCN production of CNB2∑+ system is also found. The threshold wavelength of incident photons for SCN formation is 197 ± 1 nm for CH3SCN and 188 ± 1 nm for CH3NCS. These values give D(CH3—SCN)= 3.04 eV and D(CH3—NCS)= 3.37 eV for the production of NCSA2Πi. A value of ΔHf(SCN)= 3.19 eV (76.4 kcal mol–1) has been calculated. |
| URI: | http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17451 |
| Appears in Collections: | Journal Articles (before-1995) |
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| File | Description | Size | Format | |
|---|---|---|---|---|
| 940-946.pdf Restricted Access | 904.15 kB | Adobe PDF | View/Open Request a copy |
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