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Please use this identifier to cite or link to this item: http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17451
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dc.contributor.authorD’Amario, P.-
dc.contributor.authorStefano, G. Di-
dc.contributor.authorLenzi, M.-
dc.contributor.authorMele, A.-
dc.date.accessioned2025-02-10T15:15:34Z-
dc.date.available2025-02-10T15:15:34Z-
dc.date.issued1972-
dc.identifier.urihttp://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17451-
dc.description.abstractPhotolysis of CH3NCS and CH3SCN in the vacuum u.-v. produces fluorescence attributed to SCN excited radicals. In the case of CH3SCN production of CNB2∑+ system is also found. The threshold wavelength of incident photons for SCN formation is 197 ± 1 nm for CH3SCN and 188 ± 1 nm for CH3NCS. These values give D(CH3—SCN)= 3.04 eV and D(CH3—NCS)= 3.37 eV for the production of NCSA2Πi. A value of ΔHf(SCN)= 3.19 eV (76.4 kcal mol–1) has been calculated.en_US
dc.language.isoenen_US
dc.publisherJournal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (5)en_US
dc.subjectChemistryen_US
dc.subjectPhotodissociationen_US
dc.subjectMethyl Thiocyanate and Isothiocyanateen_US
dc.subjectVacuum Ultraviolet (VUV) Radiationen_US
dc.subjectExcited Productsen_US
dc.subjectJournal of the Chemical Society : Faraday Transaction - Ien_US
dc.titleExcited Products in the Photodissociation of Methyl Thiocyanate and Isothiocyanate in the Vacuum Ultra-violeten_US
dc.typeArticleen_US
Appears in Collections:Journal Articles (before-1995)

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