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Please use this identifier to cite or link to this item: http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17457
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dc.contributor.authorIse, Norio-
dc.contributor.authorMatsuda, Yoshinobu-
dc.date.accessioned2025-02-10T15:16:19Z-
dc.date.available2025-02-10T15:16:19Z-
dc.date.issued1973-
dc.identifier.urihttp://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17457-
dc.description.abstractThe aquation reaction of Co(NH3)5Br2+ was studied kinetically with Ag’, Hg2 *, and Tl3+ as inducing cations. Addition of polyethylene sulphonate, polystyrene sulphonate and polyphosphate markedly enhanced the reaction. The acceleration factor, ranging from 10 to 104, was dependent on the inducing cations, polyclcctrolytes, their concentrations and the concentrations of foreign salts. The enthalpy of activation (AJ/*) and the entropy of activation (AS*) were decreased by addition of polyclcctrolytes in the case of Agh and Hg2*, as has been observed previously, whereas A//* was not influenced and AS* increased in the case of Tl3*. The behaviour of Tl3+ was ascribed to the strong hydration of this cation.en_US
dc.language.isoenen_US
dc.publisherJournal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (1)en_US
dc.subjectChemistryen_US
dc.subjectPolyelectrolytesen_US
dc.subjectAquation Reactionen_US
dc.subjectJournal of the Chemical Society : Faraday Transaction - Ien_US
dc.titleCatalysis by Polyelectrolytes of the Ag+, Hg2+, and Tl3+ Induced Aquations of Co(NH3)5Br2 +en_US
dc.typeArticleen_US
Appears in Collections:Journal Articles (before-1995)

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