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http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17469| Title: | Reaction of Hydrogen Atoms with Nitrous Oxide |
| Authors: | Baldwin, R. R. Gethin, A. Walker, R. W. |
| Keywords: | Chemistry Hydrogen Atoms Nitrous Oxide Reactions Radical Reactions Reaction Mechanisms Journal of the Chemical Society : Faraday Transaction - I |
| Issue Date: | 1973 |
| Publisher: | Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (2) |
| Abstract: | The velocity constant of the reaction H + N2O → N2+ OH (22) has been obtained at 500°C by the addition of N2O to slowly reacting mixtures of H2+ O2+ He and measurement of the relative rates of formation of N2 and H2O. The ratio k22/k2= 0.64 ± 0.07 gives k22= 2.6 × 106 l. mol–1 s–1, the error of ± 30–40% being largely due to the uncertainty in k2. H + O2→ OH + O. (2) Combination with other measurements gives the Arrhenius parameters A22= 7.6 × 1010 l. mol–1 s–1, E22= 15.1 ± 1.0 kcal mol–1. |
| URI: | http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17469 |
| Appears in Collections: | Journal Articles (before-1995) |
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|---|---|---|---|---|
| 352-358.pdf Restricted Access | 563.4 kB | Adobe PDF | View/Open Request a copy |
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