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dc.contributor.authorBaxendale, J. H.-
dc.contributor.authorWardman, Peter-
dc.date.accessioned2025-02-11T07:16:54Z-
dc.date.available2025-02-11T07:16:54Z-
dc.date.issued1973-
dc.identifier.urihttp://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17472-
dc.description.abstractThe spectra due to electrons in alcohols at temperatures near their melting points show absorptions in the far and infra-red which, in general, decay to produce increased absorptions in the visible. At these temperatures the time for these changes increases in the order methanol, ethanol, n-butyl, isopropyl, n-propyl alcohol. For the latter the half-life of the absorption decay is given by τs=A exp E/RT where log10A=–15.7 and E= 25 kJ (5.9 kcal). Addition of solutes which react with electrons decreases the initial infra-red absorption and is interpreted as reaction with electrons before they become solvated. The observations are discussed in terms of molecular relaxation and electron migrationen_US
dc.language.isoenen_US
dc.publisherJournal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (3)en_US
dc.subjectChemistryen_US
dc.subjectElectronsen_US
dc.subjectLiquid Alcoholsen_US
dc.subjectLow Temperaturesen_US
dc.subjectJournal of the Chemical Society : Faraday Transaction - Ien_US
dc.titleElectrons in Liquid Alcohols at Low Temperaturesen_US
dc.typeArticleen_US
Appears in Collections:Journal Articles (before-1995)

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