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DC Field | Value | Language |
---|---|---|
dc.contributor.author | Baxendale, J. H. | - |
dc.contributor.author | Wardman, Peter | - |
dc.date.accessioned | 2025-02-11T07:16:54Z | - |
dc.date.available | 2025-02-11T07:16:54Z | - |
dc.date.issued | 1973 | - |
dc.identifier.uri | http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17472 | - |
dc.description.abstract | The spectra due to electrons in alcohols at temperatures near their melting points show absorptions in the far and infra-red which, in general, decay to produce increased absorptions in the visible. At these temperatures the time for these changes increases in the order methanol, ethanol, n-butyl, isopropyl, n-propyl alcohol. For the latter the half-life of the absorption decay is given by τs=A exp E/RT where log10A=–15.7 and E= 25 kJ (5.9 kcal). Addition of solutes which react with electrons decreases the initial infra-red absorption and is interpreted as reaction with electrons before they become solvated. The observations are discussed in terms of molecular relaxation and electron migration | en_US |
dc.language.iso | en | en_US |
dc.publisher | Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (3) | en_US |
dc.subject | Chemistry | en_US |
dc.subject | Electrons | en_US |
dc.subject | Liquid Alcohols | en_US |
dc.subject | Low Temperatures | en_US |
dc.subject | Journal of the Chemical Society : Faraday Transaction - I | en_US |
dc.title | Electrons in Liquid Alcohols at Low Temperatures | en_US |
dc.type | Article | en_US |
Appears in Collections: | Journal Articles (before-1995) |
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File | Description | Size | Format | |
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582-602.pdf Restricted Access | 1.23 MB | Adobe PDF | View/Open Request a copy |
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