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http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17560| Title: | Kinetics and Thermodynamics of the Proton-transfer Reactions of 2,4-Dinitrophenol with some Amine Bases in Chlorobenzene studied by a Microwave Temperature-jump Method |
| Authors: | Caldin, Edward F. Crooks, John E. Donnell, Derek O’ |
| Keywords: | Chemistry Proton-Transfer Reactions Kinetics Thermodynamics Microwave Temperature-Jump Method Journal of the Chemical Society : Faraday Transaction - I |
| Issue Date: | 1973 |
| Publisher: | Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (6) |
| Abstract: | The proton-transfer reactions of 2,4-dinitrophenol with trimethylamine, tri-n-octylamine, quinuclidine and triethylenediamine in chlorobenzene at 25CC have been studied. Equilibrium constants have been determined spectrophotometrically, and rate constants for some of the reactions have been determined by means of a microwave temperature-jump apparatus. The forward rate constants are one-tenth to one-hundredth of the value calculated for diffusion control. They do not correlate with the equilibrium constants, but appear to be related to steric factors. |
| URI: | http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17560 |
| Appears in Collections: | Journal Articles (before-1995) |
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| File | Description | Size | Format | |
|---|---|---|---|---|
| 993-999.pdf Restricted Access | 544.43 kB | Adobe PDF | View/Open Request a copy |
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