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http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17594| Title: | Influence of Specific Adsorption of Reactant and Product upon Charge-transfer Processes in Polarography: The Azobenzene-Hydrazobenzene System |
| Authors: | Pezzatini, Giovanni Guidelli, Rolando |
| Keywords: | Chemistry Specific Adsorption Charge-Transfer Processes Journal of the Chemical Society : Faraday Transaction - I |
| Issue Date: | 1973 |
| Publisher: | Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (4) |
| Abstract: | An examination of the polarograms of azobenzene and hydrazobenzene in media of differing pH has allowed conclusions as to the mechanism of the azobenzene-hydrazobenzene electrode process on mercury to be drawn. The shifts of the above polarograms towards increasing overpotentials with an increase in the reactant concentration have been attributed to azobenzene adsorption. A quantitative examination of this effect has allowed the value K0= 2.8 × 103 l. mol–1 to be attributed to the adsorption coefficient of azobenzene in a pH 9, 90 %(v/v) ethanol + water mixture. |
| URI: | http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17594 |
| Appears in Collections: | Journal Articles (before-1995) |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| 794-805.pdf Restricted Access | 1.32 MB | Adobe PDF | View/Open Request a copy |
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