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Please use this identifier to cite or link to this item: http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17649
Title: Stability Constants of Some Complexes of t-Butyl Mesityl Nitroxide
Authors: Burnett, George M.
Cameron, G. Gordon
Cameron, James
Keywords: Chemistry
Cameron
t-Butyl Mesityl Nitroxide
Journal of the Chemical Society : Faraday Transaction - I
Issue Date: 1973
Publisher: Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (5)
Abstract: Stability constants for complex formation of t-butyl mesityl nitroxide with various solvents and monomers have been determined in the range 25-85 C by gas-liquid chromatography and a spectrophotometric method. In general, molecules with extensive conjugation form the most stable complexes but diethyl malonate provides a notable exception. Solvents which form the most stable complexes show the strongest effects on the rate coefficients of propagation in radical polymerization of methyl methacrylate and styrene. This correlation supports the view that a proportion of the active macroradicals are complexed with monomer or solvent.
URI: http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17649
Appears in Collections:Journal Articles (before-1995)

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