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Title: | Dissociation Constant of Calcium Sulphate from 25 to 50°C |
Authors: | Ainsworth, Richard G. |
Keywords: | Chemistry Dissociation Constant Calcium Sulphate Journal of the Chemical Society : Faraday Transaction - I |
Issue Date: | 1973 |
Publisher: | Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (6) |
Abstract: | The e.m.f. of the cell Ag, AgCl | CaCl2(/Hi), CaSO4(/n2) | Ca-cxchange membrane | CaCl2(0.1 mol kg-1) | AgCl, Ag has been determined at 25,40 and 50°C. Errors associated with drifting of the calcium ion-exchange electrode have been minimised by using a rapid method to determine E& and the Nernstian slope factor of the electrode pair before determining the e.m.f. of the above cell. The data were used to calculate values of the thermodynamic quantities Kd, AGO, A//O, ASO and ACO for the dissociation of the CaSO4 ion-pair. |
URI: | http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17657 |
Appears in Collections: | Journal Articles (before-1995) |
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