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Title: | y-Radiolysis of Gaseous Hydrogen Sulphide in the presence of Hydrogen Chloride, Carbon Disulphide and Nitrous Oxide |
Authors: | Huyton, D. W. Woodward, T. W. |
Keywords: | Chemistry y-Radiolysis Gaseous Hydrogen Sulphide Hydrogen Chloride Carbon Disulphide Journal of the Chemical Society : Faraday Transaction - I |
Issue Date: | 1973 |
Publisher: | Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (6) |
Abstract: | Addition of HC1 to H2S increases the radiation yield of H2 G(H2) 7.0->10.0 by an electron scavenging process involving HC1 and H2S. CS2 lowers the H2 yield in pure H2S probably by reaction with hot H atoms and also scavenges the electrons in H2S + HC1 mixtures, lowering G(H2) in the process to < 7.0. Electron scavenging by addition of N2O to H2S to produce N2 is shown to be a very complex system with surface reactions probably playing a part. |
URI: | http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17661 |
Appears in Collections: | Journal Articles (before-1995) |
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