Please use this identifier to cite or link to this item:
http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17664| Title: | Abstraction of Chlorine Atoms from Alkyl Chlorides by the Trimethylsilyl Radical |
| Authors: | Cadman, P. Tilsley, G. M. Dickenson, A. F. Trotman |
| Keywords: | Chemistry Abstraction Chlorine Atoms Alkyl Chlorides Journal of the Chemical Society : Faraday Transaction - I |
| Issue Date: | 1973 |
| Publisher: | Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (5) |
| Abstract: | The relative rates of chlorine atom abstraction from alkyl chlorides by the trimethylsilyl radical have been studied by a competitive technique between 400 and 580 K in the gas phase. These results have been put on an absolute basis by comparing the rate of abstraction of chlorine from ethyl chloride by trimethylsilyl radicals with their rate of combination to hexamethyldisilane. Using the known rate of combination of trimethylsilyl radicals, the following Arrhenius parameters for chlorine abstraction were obtained: [graphic omitted] The results of the chlorine abstractions by the trimethylsilyl radicals are compared with those for sodium atoms and for trichlorosilyl radicals. |
| URI: | http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17664 |
| Appears in Collections: | Journal Articles (before-1995) |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| 914-921.pdf Restricted Access | 743.17 kB | Adobe PDF | View/Open Request a copy |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.