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Title: | Nuclear Magnetic Resonance Studies of Preferential Solvation: Part 2.—Thermodynamic Treatment and application to Methanol + Water Solvents |
Authors: | Covington, Arthur K. Newman, Kenneth E. |
Keywords: | Chemistry Magnetic Resonance Studies Methanol Water Solvents Journal of the Chemical Society : Faraday Transaction - I |
Issue Date: | 1973 |
Publisher: | Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (5) |
Abstract: | Prom a detailed consideration oi the thermodynamics of preferential solvation of ions in a binary solvent mixture, making reasonable assumptions about the variation of chemical potential of the variously solvated ions with solvent composition, it is shown how the variation of the free energy of transfer of a salt from water to mixed aqueous solvents derived from e.m.f. measurements can be related to spectroscopic information. |
URI: | http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17684 |
Appears in Collections: | Journal Articles (before-1995) |
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973-983.pdf Restricted Access | 798.63 kB | Adobe PDF | View/Open Request a copy |
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