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Please use this identifier to cite or link to this item: http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17745
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dc.contributor.authorHarrison, Lionel G.-
dc.contributor.authorPrasad, Mahendra-
dc.date.accessioned2025-02-15T04:43:01Z-
dc.date.available2025-02-15T04:43:01Z-
dc.date.issued1974-
dc.identifier.urihttp://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17745-
dc.description.abstractStudies of electrical conductivity, thermoelectric power and transport numbers in CuCl, pure or after exposure to Cl2 gas, in the range 24–240°C, have shown that all phenomena observed are caused by electronic rather than ionic conduction, except in pure CuCl above about 140°C. Two acceptor levels are identified, at 0.51 and 0.88 eV above the valence band. The former is attributed to cation vacancies; the latter, tentatively, to anion interstitials. For high concentrations of cation vacancies, the conduction below 100°C is predominantly by electrons in a narrow band at the acceptor level, the activation energy of this “hopping” process being 0.36 eV. The difference between the two acceptor levels is briefly discussed in terms of ligand field splitting of the Cu 3d orbitals.en_US
dc.language.isoenen_US
dc.publisherJournal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6)en_US
dc.subjectChemistryen_US
dc.subjectCatalytic Activityen_US
dc.subjectCopper Chloridesen_US
dc.subjectJournal of the Chemical Society : Faraday Transaction - Ien_US
dc.titleReactivity and catalytic activity of copper chlorides: Part 4.—Electrical properties and acceptor levels produced in CuCl by Cl2 gasen_US
dc.typeArticleen_US
Appears in Collections:Journal Articles (before-1995)

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