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http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17780| Title: | Reaction of Oxygen Atoms with Carbonyl Compounds: Part 3.—Ketene |
| Authors: | Mack, G. P. R. Thrush, B. A. |
| Keywords: | Chemistry Oxygen Atoms Carbonyl Compounds Journal of the Chemical Society : Faraday Transaction - I |
| Issue Date: | 1974 |
| Publisher: | Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6) |
| Abstract: | The reaction between excess atomic oxygen and ketene has been studied in a discharge flow system by product analysis and kinetically using e.p.r. and chemiluminescence. This rate constant for the initial step, which yields predominantly HCO + HCO was found to be (3.4 ± 0.3)× 1011 cm3 mol–1 s–1 at 293 K. The subsequent reactions are O + HCO → OH + CO (3), O + HCO → H + CO2(4), H + HCO → H2+ CO (5), O + OH → O2+ H. (6) |
| URI: | http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17780 |
| Appears in Collections: | Journal Articles (before-1995) |
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| File | Description | Size | Format | |
|---|---|---|---|---|
| 187-192.pdf Restricted Access | 375.85 kB | Adobe PDF | View/Open Request a copy |
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