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http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17817| Title: | Absolute Enthalpy of Hydration of the Proton using Data for Doubly-charged Complex Ions |
| Authors: | Lister, Maurice W. Nyburg, Stanley C. Poyntz, R. Barry |
| Keywords: | Chemistry Absolute Enthalpy Hydration Journal of the Chemical Society : Faraday Transaction - I |
| Issue Date: | 1974 |
| Publisher: | Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6) |
| Abstract: | The method used by Halliwell and Nyburg to estimate the absolute enthalpy of hydration of the proton using data for singly-charged ions has been extended to larger, doubly-charged, complex ions. Certain heats of solution were determined for salts containing complex ions, other data were taken from published values. The result, ΔH°298(abs. hyd.) H+(g)=– 1095 ± 20 kJ mol–1, is in close accord with that obtained previously, – 1090.8 ± 10.5 kJ mol–1. By far the largest source of uncertainty in this value is the lack of reliable lattice energies. |
| URI: | http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17817 |
| Appears in Collections: | Journal Articles (before-1995) |
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| File | Description | Size | Format | |
|---|---|---|---|---|
| 685-693.pdf Restricted Access | 661.58 kB | Adobe PDF | View/Open Request a copy |
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