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http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17836| Title: | Kinetics and Mechanism of the Reduction of Manganese(III) in Perchloric Acid at a Platinum Electrode |
| Authors: | Rosseinsky, David R. Hill, R. John |
| Keywords: | Chemistry Kinetics Manganese(III) Platinum Electrode Journal of the Chemical Society : Faraday Transaction - I |
| Issue Date: | 1974 |
| Publisher: | Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6) |
| Abstract: | The electrode kinetics at 25°C of the reduction of manganese(III) on an oxidised platinum surface confirms an unusually low transfer coefficient of 0.26. Interpretation involving a comparison with a correlation of hydrolytic constants of similar trivalent cations and their several redox potentials points to a hydroxo- or oxo-bridged transition state. The MnHi/Mn11 conditional standard electrode potential was observed to be 1.535 V at ionic strength 3.31 mol dm-3 against H2|HC1O4(3 mol dm-3), NaClO4 (0.31 mol dm-3). |
| URI: | http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17836 |
| Appears in Collections: | Journal Articles (before-1995) |
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| File | Description | Size | Format | |
|---|---|---|---|---|
| 1140-1144.pdf Restricted Access | 318.14 kB | Adobe PDF | View/Open Request a copy |
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