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Please use this identifier to cite or link to this item: http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17869
Title: Kinetics of Dissociative Recombination of Free Electrons with Hydronium Ions in Premixed Flames
Authors: Hayhurst, Allan N.
Telford, N. Roland
Keywords: Chemistry
Kinetics
Recombination
Free Electrons
Journal of the Chemical Society : Faraday Transaction - I
Issue Date: 1974
Publisher: Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (11)
Abstract: The rate coefficient for the gas phase recombination of H3O+ ions and free electrons in H3O++ e–→ neutral products has been measured in atmospheric pressure flames of H2+ O2+ N2 over the temperature range 2025–2445 K. Concentrations of ions were arrived at by sampling each flame into a mass spectrometer. The recombination coefficient was not found to vary significantly with temperature, being 4.1 ± 1.0 × 10–7 ion–1 cm3 s–1 over this temperature range. This corresponds to a cross-section (πσ2) for the process of about 1.5 × 10–18 m2.
URI: http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17869
Appears in Collections:Journal Articles (before-1995)

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