Please use this identifier to cite or link to this item:
http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17914| Title: | Kinetics of the reaction of the nickel(II) ion with pyridine-2-azo-p-dimethylaniline in t-butanol + water mixtures |
| Authors: | Caldin, Edward F. Godfrey, Peter |
| Keywords: | Chemistry Reactions Kinetics Nickel Ion Journal of the Chemical Society : Faraday Transaction - I |
| Issue Date: | 1974 |
| Publisher: | Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (12) |
| Abstract: | Rate constants and activation parameters have been determined for the reaction of the nickel(II) ion with pyridine -2-azo-p-dimethylaniline, in a series of t-butanol + water mixtures with mole fractions from 0 to 0.4 t-butanol. The rate constant at 25°C varies little with composition, but the enthalpy and entropy of activation both vary considerably, with compensation; they show maxima and minima, which are discussed in relation to theories of solvent structure. |
| URI: | http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17914 |
| Appears in Collections: | Journal Articles (before-1995) |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| 2260-2266.pdf Restricted Access | 665.77 kB | Adobe PDF | View/Open Request a copy |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.