DSpace logo

  1. BITS Pilani Institutional Repository
  2. Journal Archive Collections
  3. Journal Articles (before-1995)
Please use this identifier to cite or link to this item: http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17937
Full metadata record
DC FieldValueLanguage
dc.contributor.authorS. Brown, D. Lalage-
dc.contributor.authorConnor, Joseph A.-
dc.contributor.authorSkinner, Henry A.-
dc.date.accessioned2025-02-21T05:11:35Z-
dc.date.available2025-02-21T05:11:35Z-
dc.date.issued1974-
dc.identifier.urihttp://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/17937-
dc.description.abstractMeasurements of the heats of iodination of hexakis(trifluorophosphine)chromium(0) and of tetrakis(trifluorophosphine)nickel(0) were carried out by high temperature microcalorimetry. Standard enthalpies of formation were derived: ΔH°f(Ni(PF3)4, liq)=–961.9 ± 3 kcal mol–1(–4025 ± 12 kJ mol–1), ΔH°f(Cr(PF3)6, c)=–1446.4 ± 4 kcal mol–1(–6052 ± 17 kJ mol–1). The mean bond dissociation energies, D(Ni—PF3) and D(Cr—PF3) were evaluated as 35.2 ± 0.8 and 25.5 ± 1 kcal mol–1 respectively; these values compare very closely with the values D(Ni—CO) and D(Cr—CO) in Ni(CO)4 and Cr(CO)6.en_US
dc.language.isoenen_US
dc.publisherJournal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (09)en_US
dc.subjectChemistryen_US
dc.subjectMicrocalorimetric Studiesen_US
dc.subjectEnthalpiesen_US
dc.subjectJournal of the Chemical Society : Faraday Transaction - Ien_US
dc.titleMicrocalorimetric studies: Enthalpies of formation of Cr(PF3)6 and Ni(PF3)4en_US
dc.typeArticleen_US
Appears in Collections:Journal Articles (before-1995)

Files in This Item:
File Description SizeFormat 
1649-1652.pdf
  Restricted Access		256.41 kBAdobe PDFView/Open Request a copy
Show simple item record


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.