Please use this identifier to cite or link to this item:
http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/18202| Title: | Nuclear magnetic resonance studies of preferential solvation: Part 3.—Thermodynamic treatment involving change of solvation number, and application to dimethyl sulphoxide-containing solvents |
| Authors: | Covington, Arthur K. Lantzke, Ian R. Thain, Jennifer M. |
| Keywords: | Chemistry Nuclear Magnetic Resonance (NMR) Spectroscopy Preferential Solvation Journal of the Chemical Society : Faraday Transaction - I |
| Issue Date: | 1974 |
| Publisher: | Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (10) |
| Abstract: | Studies of 7Li and 133Cs ion n.m.r. chemical shifts in dimethyl sulphoxide (DMSO)+ water mixtures, have been interpreted in terms of a series of competitive equilibria in which the solvation number of the ions for DMSO is half that for water. It is concluded that nitrate ions are preferentially solvated by DMSO and Li+ by water. The treatment has also been applied to 133Cs shift data for sulpholan and water mixtures, and it is concluded that caesium ions are solvated by the organic component. |
| URI: | http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/18202 |
| Appears in Collections: | Journal Articles (before-1995) |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| 1869-1878.pdf Restricted Access | 604.94 kB | Adobe PDF | View/Open Request a copy |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.