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Title: | Kinetics of activated chemisorption. Part 2.—Theoretical models |
Authors: | Aharoni, Chaim Ungarish, Moshe |
Keywords: | Chemistry chemisorption Kinetics Journal of the Chemical Society : Faraday Transaction - I |
Issue Date: | 1977 |
Publisher: | Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (03) |
Abstract: | In activated chemisorption the plot of the reciprocal of the rate Z=(dq/dt)–1 against the time t is convex towards the Z axis at low t and concave at high t. This condition is satisfied if both the energy of activation, Et and the number of available sites, Nt decrease with the coverage q and if d2Et/dq2 < 0. Two models are considered: |
URI: | http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/18215 |
Appears in Collections: | Journal Articles (before-1995) |
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