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http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/18253| Title: | Reactions of hydrogen atoms and aliphatic radicals with monovalent cadmium and nickel ions as a source of hydrogen yield in some radiation chemical systems |
| Authors: | Freiberg, Mira Meyerstein, Dan |
| Keywords: | Chemistry hydrogen atoms aliphatic radicals Journal of the Chemical Society : Faraday Transaction - I monovalent cadmium radiation chemical systems |
| Issue Date: | 1977 |
| Publisher: | Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (04) |
| Abstract: | The effect of CdSO4 and NiSO4 on the radiolytic hydrogen yield and its isotopic composition in the systems H2O + CH3OH, H2O + CD3OH, D2O + CH3OD, H2O +(CH3)2CHOH, H2O +(CH3)2 CDOH and D2O +(CH3)2CHOD are reported. The results suggest that hydrogen atoms and aliphatic radicals oxidize Cd+aq and Ni+aq. Furthermore it is suggested that the reaction Cd—C(CH3)2 OH+→ CdH++(CH3)[graphic omitted] occurs in aqueous solutions. The implications of these observations on earlier results are discussed. |
| URI: | http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/18253 |
| Appears in Collections: | Journal Articles (before-1995) |
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| File | Description | Size | Format | |
|---|---|---|---|---|
| 0632-0647.pdf Restricted Access | 1.08 MB | Adobe PDF | View/Open Request a copy |
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